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Cation-radical catalyzed Diels-Alder reaction

✍ Scribed by Bellville, Dennis J.; Wirth, David W.; Bauld, Nathan L.


Book ID
120018295
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
422 KB
Volume
103
Category
Article
ISSN
0002-7863

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The intramolecular cation radical diels-
✍ Bijan Harirchian; Nathan L Bauld πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 181 KB

The first examples of intramolecular cation radical Die&-Alder reactions have been established using trienes which cyclize to hydroindane systems. The extremely high endo stereoselectivity characteristic of the cation radical Diels-Alder reaction is effectively exploited to generate trans-hydroinda