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Methyl substituent probe of the transition state for thermal decarbonylation of endo-tricyclo[3.2.1.02,4]octan-8-one

โœ Scribed by Merle A Battiste; Donna.D McRitchie; Paul G Gassman; William F Reuss III; Jonathan N Chasman; John Haywood-Farmer


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
185 KB
Volume
20
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Methyl substituent probes at the C-2 and C-2,C-4 positions of endo-tricyclo[3.2.1.0"'+] Summary. octan-8-one(l)haveprovided kinetic evidence confirming the simultaneity of C-2,C-4 cyclopropane


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## Enzymatic Kinetic Resolution of 5-Hydroxy-4-oxa-endotricyclo(5.2.1.02, 6)dec-8-en-3-ones: A Useful Approach to D-Ring Synthons for Strigol Analogues with Remarkable Stereoselectivity. -Racemic tricyclic hydroxy lactones (I) and (V) are resolved employing a lipase-catalyzed acetylation reaction