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Methyl 5-bromo-1H-indole-2-carboxylate

✍ Scribed by Butcher, Ray J. ;Jasinski, Jerry P. ;Yathirajan, H. S. ;Ashalatha, B. V. ;Narayana, B.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
998 KB
Volume
63
Category
Article
ISSN
1600-5368

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In the molecule of the title compound, C 10 H 8 ClNO 2 , the indole ring system is planar. In the crystal structure, the molecules are linked by intermolecular N-HÁ Á ÁO hydrogen bonds, forming centrosymmetric dimers.

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In the title molecule, C 17 H 14 BrNO 4 S, the methoxycarbonyl group is almost coplanar [dihedral angle = 5.89 ( 16) ] with the indole ring system, whereas the sulfonyl-bound phenyl ring is almost orthogonal to it [dihedral angle = 88.25 (6) ]. Weak C-HÁ Á ÁO, C-HÁ Á Á andinteractions link the molec

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The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.

5-Bromo-1H-indole-3-carb­aldehyde 2-thie
✍ Ali, Hapipah M. ;Abdul Halim, Siti Nadiah ;Lajis, Nordin Hj. ;Basirun, Wan Jefri 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 105 KB

In the title molecule, C 14 H 10 BrN 3 OS, the indole moiety is twisted by 36.0 (2) with respect to the disordered thienyl group and the nitrogen-bound H atoms interact with the amide O atoms of symmetry-related molecules, resulting in an N-HÁ Á ÁO hydrogen-bonded layer structure.