Metathesis reactions of allylsilanes containing bulky aromatic substituents
β Scribed by N. V. Ushakov; E. B. Portnykh; E. Sh. Finkel'shtein
- Book ID
- 112448904
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 187 KB
- Volume
- 40
- Category
- Article
- ISSN
- 1573-9171
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Novel Lewis Acid Promoted Reactions of Allylsilane Bearing Bulky Silyl Substituents and Aldehydes. -Two novel modes of reactions are disclosed for the Lewis acid promoted reaction of allylsilanes bearing bulky silyl substituents with aldehydes. The constitution of products is influenced by the natu
Cross-metathesis between a,b-unsaturated carbonyl compounds and allylsilanes with HoveydaΓs catalyst leads to functionalized allylsilanes in moderate to good yields and with excellent E/Z stereoselectivity in favor of the E-isomer.