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ChemInform Abstract: Novel Lewis Acid Promoted Reactions of Allylsilane Bearing Bulky Silyl Substituents and Aldehydes.

✍ Scribed by T. AKIYAMA; M. NAKANO; J. KANATANI; S. OZAKI

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199737047

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✦ Synopsis

Novel Lewis Acid Promoted Reactions of Allylsilane Bearing Bulky Silyl Substituents and Aldehydes.

-Two novel modes of reactions are disclosed for the Lewis acid promoted reaction of allylsilanes bearing bulky silyl substituents with aldehydes. The constitution of products is influenced by the nature of the Lewis acid used and the amount of reactants. The yields of dioxanes (V) depend on the silyl substituents. -(AKIYAMA, T.; NAKANO,

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