Cross-Metathesis Reaction: Direct Synthesis of Functionalized Allylsilanes

✍ Scribed by Samir BouzBouz; Elsa De Lemos; Janine Cossy

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 70 KB
• Volume: 344
• Category: Article
• ISSN: 1615-4150
• DOI: 10.1002/1615-4169(200208)344:6/7<627::aid-adsc627>3.0.co;2-c

✦ Synopsis

Cross-metathesis between a,b-unsaturated carbonyl compounds and allylsilanes with Hoveyda×s catalyst leads to functionalized allylsilanes in moderate to good yields and with excellent E/Z stereoselectivity in favor of the E-isomer.