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Metalloporphyrin Mixed-Valence π-Cation Radicals: Solution Stability and Properties

✍ Scribed by Brancato-Buentello, Kristin E.; Kang, Seong-Joo; Scheidt, W. Robert


Book ID
126223167
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
176 KB
Volume
119
Category
Article
ISSN
0002-7863

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## Abstract We have observed the mixed‐valence and radical cation dimer states of a glycoluril‐based molecular clip with tetrathiafulvalene (TTF) sidewalls at low concentration (1 mM) at room temperature. This molecular clip has four consecutive anodic steps in its cyclic voltammogram, which sugges