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Theoretical Analysis of the Structural and Electronic Properties of Metalloporphyrin π-Cation Radicals

✍ Scribed by Hirao, Hajime; Shaik, Sason; Kozlowski, Pawel M.


Book ID
121376747
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
219 KB
Volume
110
Category
Article
ISSN
1089-5639

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Symmetry states of metalloporphyrin π-ca
✍ James Terner; Avram Gold; Raymond Weiss; Dominique Mandon; Alfred X. Trautwein 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

Oxoferryl porphyrin π-cation radical active sites of compound I intermediates which are found in enzymes such as peroxidases and catalases have been extensively modeled by oxidized synthetic metalloporphyrins. The electronic symmetry states of these compounds were initially assigned on the basis of