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Metalloporphyrin Mixed-Valence π-Cation Radicals: Solid-State Structures

✍ Scribed by Scheidt, W. Robert; Brancato-Buentello, Kristin E.; Song, Hungsun; Reddy, K. Venugopal; Cheng, Beisong

Book ID
127323095
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
224 KB
Volume
35
Category
Article
ISSN
0020-1669

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✍ James Terner; Avram Gold; Raymond Weiss; Dominique Mandon; Alfred X. Trautwein 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

Oxoferryl porphyrin π-cation radical active sites of compound I intermediates which are found in enzymes such as peroxidases and catalases have been extensively modeled by oxidized synthetic metalloporphyrins. The electronic symmetry states of these compounds were initially assigned on the basis of