The ratio of citric acid to D-isocitric acid can be used to distinguish authentic and adulterated fruit juices. To separate DL-isocitric acid enantiomers, we used ligand exchange CE. D-Quinic acid was used as a chiral selector ligand and Mn(II), Fe(III), Co(II), Ni(II), Cu(II), and Zn(II) ions were
✦ LIBER ✦
Metal(II)–ligand molar ratio dependence of enantioseparation of tartaric acid by ligand exchange CE with Cu(II) and Ni(II)–D-quinic acid systems
✍ Scribed by Shuji Kodama; Sen-ichi Aizawa; Atsushi Taga; Tomohisa Yamashita; Tomoko Kemmei; Kentaro Suzuki; Yoshitaka Honda; Atsushi Yamamoto
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 169 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0173-0835
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## Abstract This paper deals with the use of Cu(II) complexes of L‐tartaric acid or L‐threonine as selectors for the chiral separation of drugs containing amino alcohol structure by ligand‐exchange CE. Using Cu(II) ions as a complexing agent, a series of sympathomimetics and β‐blockers were resolve