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Mechanism of change in enantiomer migration order of enantioseparation of tartaric acid by ligand exchange capillary electrophoresis with Cu(II) and Ni(II)–D-quinic acid systems

✍ Scribed by Sen-Ichi Aizawa; Shuji Kodama


Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
220 KB
Volume
33
Category
Article
ISSN
0173-0835

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Enantioseparation of DL-isocitric acid b
✍ Shuji Kodama; Atsushi Taga; Atsushi Yamamoto; Yuji Ito; Yoshitaka Honda; Kentaro 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB 👁 1 views

The ratio of citric acid to D-isocitric acid can be used to distinguish authentic and adulterated fruit juices. To separate DL-isocitric acid enantiomers, we used ligand exchange CE. D-Quinic acid was used as a chiral selector ligand and Mn(II), Fe(III), Co(II), Ni(II), Cu(II), and Zn(II) ions were