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Metalation of 1,3-dithiolanes. Mercaptan synthesis and carbonyl transposition

โœ Scribed by Wilson, Stephen R.; Georgiadis, Gregory M.; Khatri, Hiralal N.; Bartmess, John E.


Book ID
125990459
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
936 KB
Volume
102
Category
Article
ISSN
0002-7863

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Regeneration of carbonyl compounds from their 1,3-dithiolanes and dithianes was achieved using tert-butyl hydroperoxide (TBHP, aq. 70%) in high yields. Thus, an efficient, economic and experimentally simple protocol for dethioacetalization has been demonstrated.