Metal Triflate Catalyzed Conjugate Addition of Homochiral Pyrroles to α,β-Unsaturated Esters.
✍ Scribed by Canan Uenaleroglu; Baris Temelli; Ayhan S. Demir
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 21 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Pyrrole derivatives R 0120 Metal Triflate Catalyzed Conjugate Addition of Homochiral Pyrroles to α,β-Unsaturated Esters. -A series of alkylated pyrrole derivatives is synthesized from homochiral pyrroles via Y(III)-catalyzed regioselective alkylation with activated styrene derivatives. -(UENALEROGLU*, C.
📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The first example of an organocatalytic asymmetric Michael addition of aldehydes to α,β‐unsaturated thiol esters promoted by chiral diphenylprolinol silyl ether is presented. The reaction occurs with good yields, diastereoselectivity and excellent enantioselectivity.