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Metal Triflate Catalyzed Conjugate Addition of Homochiral Pyrroles to α,β-Unsaturated Esters.

✍ Scribed by Canan Uenaleroglu; Baris Temelli; Ayhan S. Demir


Publisher
John Wiley and Sons
Year
2005
Weight
21 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Pyrrole derivatives R 0120 Metal Triflate Catalyzed Conjugate Addition of Homochiral Pyrroles to α,β-Unsaturated Esters. -A series of alkylated pyrrole derivatives is synthesized from homochiral pyrroles via Y(III)-catalyzed regioselective alkylation with activated styrene derivatives. -(UENALEROGLU*, C.


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Enantioselective Organocatalytic Conjuga
✍ Shaolin Zhu; You Wang; Dawei Ma 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 184 KB 👁 1 views

## Abstract The first example of an organocatalytic asymmetric Michael addition of aldehydes to α,β‐unsaturated thiol esters promoted by chiral diphenylprolinol silyl ether is presented. The reaction occurs with good yields, diastereoselectivity and excellent enantioselectivity.