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Copper-Catalyzed Enantioselective Conjugate Addition of Grignard Reagents to α,β-Unsaturated Esters

✍ Scribed by Fernando López; Syuzanna R. Harutyunyan; Auke Meetsma; Adriaan J. Minnaard; Ben L. Feringa

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
143 KB
Volume
44
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Enantioselective Organocatalytic Conjuga
Enantioselective Organocatalytic Conjugate Addition of Aldehydes to α,β-Unsaturated Thiol Esters
✍ Shaolin Zhu; You Wang; Dawei Ma 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 184 KB

## Abstract The first example of an organocatalytic asymmetric Michael addition of aldehydes to α,β‐unsaturated thiol esters promoted by chiral diphenylprolinol silyl ether is presented. The reaction occurs with good yields, diastereoselectivity and excellent enantioselectivity.