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Metal dicyanamide layered coordination polymers with cyanopyridine co-ligands: Synthesis, crystal structures and magnetism

✍ Scribed by Miao Du; Qian Wang; Ying Wang; Xiao-Jun Zhao; Joan Ribas


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
656 KB
Volume
179
Category
Article
ISSN
0022-4596

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## Abstract The reaction of nickel thiocyanate with pyrazine in a 1:2 ratio leads to the new ligand‐rich 1:2 (ratio metal/ligand) compound [Ni(SCN)~2~(pyrazine)~2~]__~n~__ (1), in which the metal atoms are coordinated by four N atoms of pyrazine ligands and two N atoms of thiocyanate anions in a sl