Three novel 1-D coordination polymers consisting of {Mn[N(CN) 2 ] 2 } structural units and L ؍ 2 pyridines (i.e., 2), 2,2-bipyridine (i.e., 3), and 4,4-bipyridine (i.e., 4) have been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility studies. Compound
Cobalt and Copper Coordination Polymers Containing Acetylacetonato-Derived Ligands and Bidentate Pyridine Coligands: Synthesis, Crystal Structures and Magnetic Properties
✍ Scribed by Javier Atienza; Angel Gutiérrez; M. Felisa Perpiñán; Ana E. Sánchez
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 412 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.
## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~
## Abstract Manganese(II), cobalt(II), and zinc(II) coordination polymers, {[Mn(H~2~btec)(azopy)(H~2~O)~2~]·(azopy)}__~n~__ (1), {[Co(H~2~btec)(azopy)(H~2~O)~2~]·(azopy)}__~n~__ (2), and {[Zn~2.5~(btec)(azopy)(μ~3~‐OH)(H~2~O)]·H~2~O}__~n~__ (3) (H~4~btec = 1,2,4,5‐benzenetetracarboxylic acid; azopy