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One- and two-dimensional cobalt benzenecarboxylate coordination polymers containing a kinked organodiimine: Synthesis, structure, and magnetic properties

✍ Scribed by Lindsey L. Johnston; Kyalamboka A. Brown; David P. Martin; Robert L. LaDuca

Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
645 KB
Volume
882
Category
Article
ISSN
0022-2860

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The reactions of CoX 2 (X ‫؍‬ Br, Cl) with the planar, bidentate bridging ligand 2,1,3-benzothiadiazole (btd) in Me 2 CO led to the 2D coordination polymers +[CoBr 2 (btd)], n (1) and +[CoCl 2 (btd)], n (2). The structure of 1 was determined by singlecrystal X-ray crystallography. Complex 1 (C 6 H 4