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Novel Coordination Polymers Generated from Angular 2,2′-Dipyridyl Ligands and Bis(hexafluoroacetylacetonate) Copper(II): Crystal Structures and Magnetic Properties

✍ Scribed by Salomé Delgado; Aitor Barrilero; Agustín Molina-Ontoria; Manuela E. Medina; Cesar J. Pastor; Reyes Jiménez-Aparicio; José L. Priego


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
476 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.