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Multiple Regulated Assembly, Crystal Structures and Magnetic Properties of Porous Coordination Polymers with Flexible Ligands

✍ Scribed by Chang-Yan Sun; Xiang-Jun Zheng; Song Gao; Li-Cun Li; Lin-Pei Jin


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
405 KB
Volume
2005
Category
Article
ISSN
1434-1948

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## Abstract The podand ligand tris(4‐carboxy‐2‐phenoxyethyl)amine (ptaH~3~) readily reacts with Co^II^, Mn^II^ and Ni^II^ salts at room temperature to afford porous coordination polymers, {Co(ptaH)Β·5H~2~O}__~n~__ (1), {[Mn(ptaH)(H~2~O)]Β·4H~2~O}__~n~__ (2), and {[Ni(ptaH)(4H~2~O)]Β·6H~2~O}__~n~__, (3

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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(Β΅-OH)(bpy) 2 (H 2 O)](NO 3 )β€’2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]β€’2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.