Synthesis, Crystal Structures, and Magnetic Properties of 2D Manganese(II) and 1D Gadolinium(III) Coordination Polymers with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid
β Scribed by Wei Shi; Xiao-Yan Chen; Na Xu; Hai-Bin Song; Bin Zhao; Peng Cheng; Dai-Zheng Liao; Shi-Ping Yan
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 257 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4βisobutylβ3,5βdi(2βpyridyl)β4__H__β1,2,4βtriazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~
Two new polynuclear complexes of Cu II , [Cu 2 (fum)(Β΅-OH)(bpy) 2 (H 2 O)](NO 3 )β’2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Π-bipyridine) and [Cu(fum)(tmen)]β’2H 2 O (2) (tmen = N,N,NΠ,NΠ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.