Metal complexes with tripodal triisocyanide ligands
β Scribed by Matthias Tamm; F.Ekkehardt Hahn
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 62 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0162-0134
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π SIMILAR VOLUMES
The tripodal N,O ligands bis(2-pyridylmethyl)(o-hydroxybenzyl)amine (L 1 ) and bis(2-pyridylmethyl)(2-carboxyethyl)amine (L 2 ) were tested for their ligating properties towards zinc. Zinc halides yielded L 1 β’ZnΟͺHal (1aΟͺc, Hal = Cl, Br, I) and L 2 β’ZnΟͺHal (2aΟͺc, Hal = Cl, Br, I). Subsequent treatme
The solution configuration of labile coordination complexes may be difficult to determine, even in cases in which the solid state structure is known. We have previously synthesized a series of chiral ligands which form pseudo-C3-symmetric complexes with ZnII and CuII salts that possess an available