Strategies for the complexation of technetium with tripodal ligands
β Scribed by M. Tamm; S. Rupprecht; F.E. Hahn
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 57 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0162-0134
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π SIMILAR VOLUMES
## Technetium(I) complexes of trimethylphosphite (tmp), dimethylmethylphosphonite (dmmp) and methyldiethylphosphinite (mdep) have been synthesized through direct interaction of the ligand with sodium pertechnetate. The homoleptic, hexakis (ligand), cationic complexes can be isolated as tetrapheny
## Abstract The acid hydrolysis and formation kinetics of 1:1 ferric complexes with several tripodal hexadentate ligands were investigated over the [H^+^] range of 0.02β1.0 M at 25 Β°C and at an ionic strength of 2.0 M (NaClO~4~/HClO~4~). These ligands are based on a tris(2βaminoethyl)amine (TREN) s