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Complexes of technetium with polyhydric ligands

✍ Scribed by Lydia L.-Y. Hwang; Nicholas Ronca; Nathan A. Solomon; Joseph Steigman


Publisher
Elsevier Science
Year
1985
Weight
675 KB
Volume
36
Category
Article
ISSN
0020-708X

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Synthesis and characterization of techne
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## Technetium(I) complexes of trimethylphosphite (tmp), dimethylmethylphosphonite (dmmp) and methyldiethylphosphinite (mdep) have been synthesized through direct interaction of the ligand with sodium pertechnetate. The homoleptic, hexakis (ligand), cationic complexes can be isolated as tetrapheny

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2-Mercapto-methyltetrazolate, Smetetraz Β± , acts as monoanionic, monodentate ligand in a number of technetium compounds. Anionic Tc V complexes of the types [TcO(Smetetraz) 4 ] Β± and [TcN(Smetetraz) 4 ] 2Β± are formed when (Bu 4 N)[Tc V OCl 4 ] or (Bu 4 N)[Tc VI NCl 4 ], respectively, react with Na(S