Complexes of technetium with polyhydric ligands
β Scribed by Lydia L.-Y. Hwang; Nicholas Ronca; Nathan A. Solomon; Joseph Steigman
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 675 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0020-708X
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π SIMILAR VOLUMES
## Technetium(I) complexes of trimethylphosphite (tmp), dimethylmethylphosphonite (dmmp) and methyldiethylphosphinite (mdep) have been synthesized through direct interaction of the ligand with sodium pertechnetate. The homoleptic, hexakis (ligand), cationic complexes can be isolated as tetrapheny
2-Mercapto-methyltetrazolate, Smetetraz Β± , acts as monoanionic, monodentate ligand in a number of technetium compounds. Anionic Tc V complexes of the types [TcO(Smetetraz) 4 ] Β± and [TcN(Smetetraz) 4 ] 2Β± are formed when (Bu 4 N)[Tc V OCl 4 ] or (Bu 4 N)[Tc VI NCl 4 ], respectively, react with Na(S