Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) – Thermodynamic and Formation/Decomplexation Kinetic Studies
✍ Scribed by Ivona Svobodová; Jana Havlíčková; Jan Plutnar; Přemysl Lubal; Jan Kotek; Petr Hermann
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 400 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The formation and dissociation kinetics of the pentaco‐ordinated Cu^2+^, Ni^2+^, Co^2+^ and Zn^2+^ complexes with 1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane (4‐MeCyclam‐14) was studied by pH‐stat techniques and spectrophotometrically. The rates of the reactions between 4‐MeC
## Abstract The interaction of solvents and of unidentate ligands such as N, SCN^−^, OCN^−^ and OH^−^ with the Co^2+^‐, Ni^2+^ and Cu^2+^‐complexes of 1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane (TMC) have been studied by Spectrophotometric and calorimetric techniques. The spectra in dif
## Abstract The synthesis, properties and complexation of 1‐methyl‐1,4,8,11‐tetraazacyclotetradecane (1‐MeCyclam‐14), 1,5‐dimethyl‐1,5,8,12‐tetraazacyclotetradecane (2‐MeCyclam‐14) and 1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane (4‐MeCyclam‐14) are described. While the Ni^2+^ and Cu^2+^