High Thermodynamic Stability and Extraordinary Kinetic Inertness of Copper(II) Complexes with 1,4,8,11-Tetraazacyclotetradecane-1,8-bis(methylphosphonic acid): Example of a Rare Isomerism between Kinetically Inert Penta- and Hexacoordinated Copper(II) Complexes

A comparative kinetic study for the oxid

A comparative kinetic study for the oxidation of 2-mercaptoethanol by di-μ-oxo-bis(1,4,7,10-tetraazacyclododecane)-dimanganese(III,IV) and di-μ-oxo-bis(1,4,8,11-tetraazacyclotetradecane)-dimanganese(III,IV) complexes: Influence of copper(II)

✍ Sanchita Goswami; Nizamuddin Shaikh; Anangamohan Panja; Pradyot Banerjee 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

## Abstract A comparative kinetic study of the reactions of two mixed valence manganese(III,IV) complexes with macrocyclic ligands, [L^1^Mn^IV^(O)~2~Mn^III^L^1^], **1** (L^1^ = 1,4,7,10‐tetraazacyclododecane) and [L^2^Mn^IV^(O)~2~Mn^III^L^2^], **2** (L^2^ = 1,4,8,11‐tetraazacyclotetradecane) with 2