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Metal complexes containing the trimethylamine-carboxylatoborane ligand: synthesis and characterization of [M3O((CH3)3N.BH2CO2)6R3]+X- (M = Cr(III), Fe(III); R = H2O, CH3OH; X- = NO3-, Cl-)

✍ Scribed by Norwood, Verrill M.; Morse, Karen W.

Book ID
126227437
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
546 KB
Volume
25
Category
Article
ISSN
0020-1669

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## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds.