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Metal-catalysed reactions of benzhydryl 6-diazopenicillanate with alcohols

โœ Scribed by Matlin, Stephen A.; Chan, Lam

Book ID
118205390
Publisher
The Royal Society of Chemistry
Year
1980
Tongue
English
Weight
232 KB
Volume
17
Category
Article
ISSN
0022-4936

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The BF3.Et20 catalysed reactions of the diazopenicillanate 1 with ketones provide novel 6-acyl-6-alkyl(aryl)penicillanates 2, together with thiazolooxazinones 6 formed via penam C(5)-C(6) cleavage reactions.