Reactions of 6-diazopenicillanates with allylic sulphides, selenides, and bromides
✍ Scribed by Peter J. Giddings; John D. Ivor; Eric J. Thomas
- Book ID
- 104237213
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 235 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract An efficient and mild reaction for introducing an allylic moiety and an alkylthio‐ or alkylseleno‐group onto the α‐carbon of β‐dicarbonyl compounds in one step by tandem transylidation and [2,3]‐sigmatropic rearrangement is described.
## Abstract The ion–molecule reactions of allyl bromide with the molecular ion of allyl bromide and with its major fragment, the allyl ion, yield the C~6~H~7~^+^ and C~6~H~9~^+^ ions. The structure of these product ions was explored by means of photofragmentation with laser light in the 10 μm regio