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Reaction of phenyliodonium ylides of β-dicarbonyl compounds with allylic sulfides and selenides

✍ Scribed by Rui-Yang Yang; Li-Xin Dai; Ru-Jian Ma

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 332 KB
Volume: 3
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520030521

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✦ Synopsis

Abstract

An efficient and mild reaction for introducing an allylic moiety and an alkylthio‐ or alkylseleno‐group onto the α‐carbon of β‐dicarbonyl compounds in one step by tandem transylidation and [2,3]‐sigmatropic rearrangement is described.

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