𝔖 Bobbio Scriptorium
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Metabolism of 3β-Hydroxy-5β-(3α-3H)-cholest-7-en-6-one in Calliphora stygia

✍ Scribed by D.H.S. Horn; E.J. Middleton; J.A. Thomson; J.S. Wilkie


Book ID
113167467
Publisher
Elsevier Science
Year
1976
Weight
317 KB
Volume
6
Category
Article
ISSN
0020-1790

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Reaction of 36-benzyloxy-5-hydroxy-5a-cholestan-6-one (1) with potassium t-butoxide in t-butyl alcohol gives 5-hydroxy-56-cholest-3-en-6-one (2), which on direct irradiation (300 nm) ?-n hexanes gives the B-seco steroid 9 and the indenacetaldehyde derivative 10.