✦ LIBER ✦

Synthesis and photochemistry of 5-hydroxy-5β-cholest-3-en-6-one

✍ Scribed by Shirley Stiver; Peter Yates

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 184 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84490-1

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of 36-benzyloxy-5-hydroxy-5a-cholestan-6-one (1) with potassium t-butoxide in t-butyl alcohol gives 5-hydroxy-56-cholest-3-en-6-one (2), which on direct irradiation (300 nm) ?-n hexanes gives the B-seco steroid 9 and the indenacetaldehyde derivative 10.

📜 SIMILAR VOLUMES

Synthesis of (±), (+), and (−)3β-(1-Phen

Synthesis of (±), (+), and (−)3β-(1-Phenylethylamino)cholest-5,6-enes

✍ Jasbir K. Anand; Sam F. Boyce 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 366 KB 👁 1 views

Steroids, XLVII: A facile synthesis of 3

Steroids, XLVII: A facile synthesis of 3β-hydroxy-5α-cholest-8(14)-en-15-one

✍ Tamás Bakos; Judit Horváth; Irén Vincze 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 303 KB

The synthesis of 3β-hydroxy-4,4-dimethyl

The synthesis of 3β-hydroxy-4,4-dimethyl-5α-cholest-8-en-11-one from lanosterol

✍ C.W. Shoppee; N.W. Hughes; Ruth E. Lack 📂 Article 📅 1966 🏛 Elsevier Science 🌐 French ⚖ 98 KB

Identification of 3β-hydroxy-5α-cholest-

Identification of 3β-hydroxy-5α-cholest-6-ene-5-hydroperoxide in human oxidized LDL

✍ D. Caruso; M.F. Rasetti; L. De Angelis; G. Galli 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 408 KB

Oxidized LDL exhibits cytotoxic activity towards endothelial cells, which is thought to be mediated by the products derived also from cholesterol oxidation, mainly involving the B-ring. By LC-PB-EI-MS and El-MS/MS analysis, we have identified 3fl-hydroxy-5~-cholest-6-ene-5-hydroperoxide among the ch

ChemInform Abstract: Selenium Dioxide Ox

ChemInform Abstract: Selenium Dioxide Oxidation of 3β-Benzoyloxy-5α-cholest-8(14)-en-15-one: Chemical Synthesis of 3β-Hydroxy-5α-cholest-8(14),16-dien-15-one.

✍ Hong-Seok Kim; Jung-Ho Kang 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

The dehydrochlorination of 3β-chloro-5β-

The dehydrochlorination of 3β-chloro-5β-cholestane. New syntheses of 5β-cholest-2-ene and 5β-cholest-3-ene

✍ G. Bellucci; F. Macchia; V. Malaguzzi 📂 Article 📅 1966 🏛 Elsevier Science 🌐 French ⚖ 238 KB

Although most cholestenes of the 56 series have been throughly investigatea' only few informations can be found in the literature about the analogous 5P-derivatives. It has been reported, for instance, that 5)3-cholestan-3/j-01 tosylate is transformed by alumina into 5P-cholest-2-ene,' and that the