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Meta-substituent effects on benzyl free-radical stability

✍ Scribed by Fisher, Thomas H.; Dershem, Stephen M.; Prewitt, M. Lynn

Book ID
118006478
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
541 KB
Volume
55
Category
Article
ISSN
0022-3263

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Substituent effects and free radical sta
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We report a kinetic study which indicates that the stabilizing effect of the methoxy group in a pure rsdieal system is small. The rates of d~com~s~tion of I (diphenyl ether, l.50Β° to 180Β° C) and II (toluene, 50' to 80' C) were monitored by measuring nitrogen evolution using a constsnt volume variab