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Mercury in organic chemistry. 25. Rhodium(I)-catalyzed alkenylation of arylmercurials

✍ Scribed by Larock, R. C.; Narayanan, K.; Hershberger, S. S.

Book ID
120395130
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
517 KB
Volume
48
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Mercury in organic chemistry. 19. Rhodiu
Mercury in organic chemistry. 19. Rhodium promoted methylation of organomercurials
✍ R.C. Larock; S.S. Hershberger πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 178 KB

Alkenyl-, alkynyl-and arylmercurials are methylated in excellent yield upon treatment with stoichiometric amounts of CHaRhI2(PPha)z (1). these organomercurials is possible using 1 and methyl iodide, Catalytic methylation of but side reactions interfere.