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Rhodium(I)?sulfonated-bdpp catalysed asymmetric hydrogenation of imines in aqueous?organic two-phase solvent systems

✍ Scribed by Bakos, J�zsef; Orosz, �rp�d; Heil, B�lint; Laghmari, Mohamed; Lhoste, Paul; Sinou, Denis


Book ID
120611746
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
205 KB
Volume
23
Category
Article
ISSN
0022-4936

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Influence of degree of sulfonation of BD
✍ Cornelis Lensink; Evelien Rijnberg; Johannes G. de Vries 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 672 KB

Asymmetric hydrogenation experiments were carried out with catalysts prepared in situ from [Rh(COD)CI], and 2 eq. of a sulfonated (2S,4S)-bis-2,4-(diphenylphosphino)pentane carrying O-4 sulfonate groups, in a two phase aqueous organic system. The effect of degree of sulfonation on enantioselectivity