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Mercury in organic chemistry. 19. Rhodium promoted methylation of organomercurials

✍ Scribed by R.C. Larock; S.S. Hershberger

Book ID: 104244043
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 178 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92928-4

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✦ Synopsis

Alkenyl-, alkynyl-and arylmercurials are methylated in excellent yield upon treatment with stoichiometric amounts of CHaRhI2(PPha)z (1). these organomercurials is possible using 1 and methyl iodide, Catalytic methylation of but side reactions interfere.

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