✦ LIBER ✦

Megawatt infrared laser photochemistry of ketene

✍ Scribed by W.A. Jalenak; D. Schultz; M. Fisher; N.S. Nogar

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 400 KB
Volume: 64
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80221-3

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✦ Synopsis

Multiphoton krser-induced decomposition is reported here for photolysis of ketene with 9.260 pm radiation from a pulsed CO2 TEA laser. Chemical end products of this photolysis were primanly Ha and CO. Visible chemihtminescence, attributed to Ca Swan band emission, wns observed during the fust = 1 ps folIowin,o photolysis. A collision-assisted dissociation, fol-Ioned by rcphotolysis of the transient products, is proposed to account for the results.

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