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Medium and solvent effects on the kinetics of chloride-bromide exchange at tetrahedral tetrahaloferrates(III)

✍ Scribed by Gerben P Algra; Sijbe Balt

Book ID: 108324268
Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 713 KB
Volume: 83
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)82390-7

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## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0°C and I = 0.10 mol dm^−3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ · CoOCOCO~2~Ni]^3+^ in wh