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Solvent effect on the kinetics of the chlorine isotopic exchange reaction between chloride ion and O,O-diphenyl phosphorochloridate or O,O-diphenyl phosphorochloridothioate

✍ Scribed by Mikolajczyk, M.; Slebocka-Tilk, H.; Reimschuessel, W.

Book ID
126843383
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
633 KB
Volume
47
Category
Article
ISSN
0022-3263

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## Abstract The kinetics of replacement of H~2~O by [Ru(NH~3~)pz]^2+^ (pz = pyrazine) in [Fe(CN)~5~H~2~O]^3−^ have been studied in various concentrated electrolyte solutions and in various water–cosolvent mixtures, at 298 K. Salt and cosolvent effects can be rationalized taking into account specifi