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Effect of pressure on the kinetics of the exchange of oxygen-18 between hexaaquochromium(III) ion and solvent water. Evidence for an associative interchange mechanism

✍ Scribed by Swaddle, T. W.; Stranks, D. R.


Book ID
126042264
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
293 KB
Volume
93
Category
Article
ISSN
0002-7863

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High-Pressure 17O-NMR. Study of Vanadium
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## Abstract The water exchange of [V(H~2~O)~6~]Cl~2~ in aqueous solution has been studied as a function of temperature and pressure (up to 250 MPa), by measuring the ^17^O‐FT‐NMR. line‐widths of the free water resonance at 8.13 MHz. The kinetic parameters obtained are __K__ = 87Β±4 s^βˆ’1^, __Ξ”H__^\*^