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Mechanistic Study of Nickel-Catalyzed Ynal Reductive Cyclizations through Kinetic Analysis

โœ Scribed by Baxter, Ryan D.; Montgomery, John

Book ID
126165684
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
917 KB
Volume
133
Category
Article
ISSN
0002-7863

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## Abstract The kinetics and mechanism of the formation of an antitubercular complex [Fe(CN)~5~(INH)]^3โˆ’^ based on the substitution reaction between K~4~[Fe(CN)~6~] and isoniazid (INH), i.e., isonicotinohydrazide, catalyzed by Hg^2+^ in aqueous medium was studied spectrophotometrically at 435 nm (t