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Hammett Study on the TiO2-Catalyzed Photooxidation of Para-Substituted Phenols. A Kinetic and Mechanistic Analysis

✍ Scribed by O'Shea, Kevin E.; Cardona, Claudia


Book ID
126924401
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
626 KB
Volume
59
Category
Article
ISSN
0022-3263

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The kinetics of chlorination of a number of ortho-, meta-, and para-substituted phenols by N-chloro-3-methyl-2,6-diphenylpiperidin-4-one (NCP) in acid medium have been investigated. The reaction is of first order with respect to oxidant and the order with respect to the substrate varies depending o