Kinetic and mechanistic studies of propene dimerization catalyzed by silica-supported nickel complexes
β Scribed by Christine Lepetit; Jean-Yves Carriat; Carroll Bennett
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 628 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0926-860X
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π SIMILAR VOLUMES
The kinetics of the oxidation of thiosulfate ion by [Mn(Y)I ~ (H4Y = trans-cyclohexane-l,2-diamine-N,N,N',N'-tetraacetic acid) and [Ni(L1)I2+ (HL1 = 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2one oxime) have been investigated at 20.0, 30.0, and 40.0"C in aqueous solution and found to follow
The kinetics of complexation of Ni(II) by pterin was studied in aqueous solutions with a stopped-flow apparatus under conditions of pseudo-first order in the temperature range 5-45ΠC, pH between 4.0 and 6.5, and ionic strength 0.4 M. The equilibrium constants, stoichiometry, and pK a of the ligand a