𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanistic Studies on Thiaminase I. 3. Stereochemistry of the Thiaminase I and the Bisulfite-Catalyzed Degradation of Chiral Monodeuteriothiamin

✍ Scribed by Nicewonger, Robb; Costello, Colleen A.; Begley, Tadhg P.

Book ID
118048061
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
149 KB
Volume
61
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Mechanistic Studies on Thiaminase I: Ide
Mechanistic Studies on Thiaminase I: Identification of the Product of Thiamin Degradation in the Absence of the Nucleophilic Cosubstrate
✍ Min Wu; Elizabeth T. Papish; Tadhg P. Begley πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 46 KB

Thiaminase I catalyzes the decomposition of thiamin under basic conditions in the absence of the nucleophilic cosubstrate. The product of this reaction was identified as the adduct resulting from the displacement of the thiazole moiety of thiamin by the ring opened form of thiamin.

Aminomethyl and Aminoacetyl Complexes of
Aminomethyl and Aminoacetyl Complexes of Palladium(II), Platinum(II), Iron(II) and Rhenium(I) with N-Phthaloyl as Amino Protecting Group and Mechanistic Studies on the Palladium-Catalyzed Amidocarbonylation
✍ Armin Enzmann; Markus Eckert; Walter Ponikwar; Kurt Polborn; Stefan Schneiderbau πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 252 KB πŸ‘ 2 views

## Abstract New aminomethyl and aminoacetyl complexes with __N__‐phthaloyl as the amino protecting group were synthesised by oxidative addition of __N__‐phthaloylmethyl or ‐acetyl halide to carbonylmetallates or to Pd(PPh~3~)~4~ or [Pt(C~2~H~4~)(PPh~3~)~2~] to give [Re{C(O)CH~2~N‐phthaloyl}(CO)~5~]