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Mechanistic possibilities for oxetane formation in the biosynthesis of Taxol’s D ring

✍ Scribed by Dan Willenbring; Dean J. Tantillo


Book ID
111459631
Publisher
Springer
Year
2008
Tongue
English
Weight
693 KB
Volume
78
Category
Article
ISSN
1070-3632

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MI ## M4 Scheme 1 were treated with equal amounts of acetic acid under identical reaction conditions (20 "C, 2 h). The yields of the cyclic tetrapyrroles were determined by HPLC with 5,5,10,10,15,15,20,20-octamethylporphyrinogen as internal The reaction of 2 gave no identifiable products; 3 prov