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Biosynthesis of rotenoids. Evidence for 1,2-aryl migration and the isoflavonoid construction of rings A, C, and D in rotenone and amorphigenin

โœ Scribed by Crombie, L.; Thomas, M. B.


Book ID
121512068
Publisher
The Royal Society of Chemistry
Year
1967
Tongue
English
Weight
908 KB
Category
Article
ISSN
0022-4952

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A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue