Mechanistic investigations with positive halogens; kinetics of oxidation of thiosemicarbazide by chloramine-B, bromamine-B and dichloramine-B in acid medium.
โ Scribed by B. Thimme Gowda; J. Ishwara Bhat
- Book ID
- 108371597
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 653 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4020
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๐ SIMILAR VOLUMES
The kinetics of oxidation of the aliphatic primary amines, n-propylarnine, n-butylarnine, and isoarnylarnine, by sodium N-brornobenzenesulfonarnide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35" C The reaction rate shows a First-order dependence each on [ BABl and [amine]. a
The kinetics of oxidation of Norfloxacin [1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(lpiperazinyl)-3-quinoline carboxylic acid] by chloramine-B and N-chlorobenzotriazole has been studied in aqueous acetic acid medium (25% v/v) in the presence of perchloric acid at 323 K. For both the oxidants, the reacti
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะC. In the presence of the catalyst, the experimental rate law