Mechanistic investigation of oxidation of a diketone by bromamine-B in acid medium
โ Scribed by T. Asha Iyengar; D. S. Mahadevappa; Puttaswamy
- Book ID
- 112907658
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 334 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0253-4134
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๐ SIMILAR VOLUMES
The kinetics of oxidation of the aliphatic primary amines, n-propylarnine, n-butylarnine, and isoarnylarnine, by sodium N-brornobenzenesulfonarnide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35" C The reaction rate shows a First-order dependence each on [ BABl and [amine]. a
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะC. In the presence of the catalyst, the experimental rate law