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Mechanistic Investigations of Imine Hydrogenation Catalyzed by Cationic Iridium Complexes

✍ Scribed by Marta Martín; Eduardo Sola; Santiago Tejero; José L. Andrés; Luis A. Oro

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
426 KB
Volume
12
Category
Article
ISSN
0947-6539

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✍ Marta Martín; Eduardo Sola; Santiago Tejero; José A. López; Luis A. Oro 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 1 views

## Abstract Treatment of [Ir~2~(μ‐H)(μ‐Pz)~2~H~3~(NCMe)(P__i__Pr~3~)~2~] (1) with one equivalent of HBF~4~ or [PhNHCHPh]BF~4~ affords efficient catalysts for the homogeneous hydrogenation of __N__‐benzylideneaniline. The reaction of 1 with HBF~4~ leads to the trihydride–dihydrogen complex [Ir~2~(μ