Transfer Hydrogenation of Imines Catalyzed by a Nickel(0)/NHC Complex.
✍ Scribed by Sebastien Kuhl; Raphael Schneider; Yves Fort
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 117 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Treatment of [Ir~2~(μ‐H)(μ‐Pz)~2~H~3~(NCMe)(P__i__Pr~3~)~2~] (1) with one equivalent of HBF~4~ or [PhNHCHPh]BF~4~ affords efficient catalysts for the homogeneous hydrogenation of __N__‐benzylideneaniline. The reaction of 1 with HBF~4~ leads to the trihydride–dihydrogen complex [Ir~2~(μ