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ChemInform Abstract: Asymmetric Hydrogenation of Imines Catalyzed by Carboxylato( diphosphine)iridium(III) Complexes.

✍ Scribed by R. SABLONG; J. A. OSBORN

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract Treatment of [Ir~2~(μ‐H)(μ‐Pz)~2~H~3~(NCMe)(P__i__Pr~3~)~2~] (1) with one equivalent of HBF~4~ or [PhNHCHPh]BF~4~ affords efficient catalysts for the homogeneous hydrogenation of __N__‐benzylideneaniline. The reaction of 1 with HBF~4~ leads to the trihydride–dihydrogen complex [Ir~2~(μ